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Year 2023, Volume: 62 Issue: 4, 175 - 182, 12.02.2024

Emrah Durgut Mustafa Çınar Orhan Özdemir

https://doi.org/10.30797/madencilik.1364137

Abstract

References

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  • https://doi.org/10.19111/bmre.44287
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  • Churchman, G.J., Pasbakhsh, P., Lowe, D.J., Theng, B.K.G. 2016. Unique but diverse: some observations on the formation, structure and morphology of halloysite. Clay Minerals 51, 395-416. https://doi.org/10.1180/ claymin.2016.051.3.14
  • Chorover, J., Sposito, G., 1995. Surface charge characteristics of kaolinitic tropical soils. Geochimica et Cosmochimica Acta 59, 875-884. https:// doi.org/10.1016/0016-7037(94)00357-2
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  • Cravero, F., Maiza, P.J., Marfil, S.A. 2012. Halloysite in Argentinian deposits: origin and textural constraints. Clay Minerals 47(3), 329-340. https:// doi.org/10.1180/claymin.2012.047.3.04
  • Delvaux, B., Tessier, D., Herbillon, A., Burtin, G., Jaunet, A.-M., Vielvoye, L. 1992. Morphology, texture, and microstructure of halloysitic soil clays as related to weathering and exchangeable cation. Clays and Clay Minerals 40(4), 446-456. https://doi.org/10.1346/CCMN.1992.0400409
  • Demir, T.U., Altaş A. 2017. Determination of Tabanköy halloysite’s characteristics. 17.National Clay Symposium, 4-7 October 2017 Muğla, Muğla Sıtkı Koçman University, e-ISBN: 978-605-4397-62-4.
  • Dixon, J.B., McKee, T.R. 1974. Internal and external morphology of tubular and spheroidal halloysite particles. Clays and Clay Minerals 22, 127- 137. https://doi.org/10.1346/CCMN.1974.0220118
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Özdemir, O. 2022a.
  • Evaluation of different dispersants on the dispersion/sedimentation behavior of halloysite, kaolinite, and quartz suspensions in the enrichment of halloysite ore by mechanical dispersion. Minerals 20(11), 1426. https://doi.org/10.3390/min12111426
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Boylu. F., Özdemir, O. 2022b. Effect of blunging/dispersion parameters on separation of halloysite nanotubes from gangue minerals. Minerals 12(6), 683. https:// doi.org/10.3390/min12060683
  • Ece, O.I., Schroeder, P.A. 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area, Balikesir, Turkey. Clays and Clay Minerals 55(1), 18-35. https://doi.org/10.1346/CCMN.2007.0550102
  • Ece, O.I., Schroeder, P.A., Smilley, M.J., Wampler, J.M. 2008. Acid-sulphate hydrothermal alteration of andesitic tuffs and genesis of halloysite and alunite deposits in the Biga Peninsula, Turkey. Clay Minerals 43(2), 281-315. https://doi.org/10.1180/claymin.2008.043.2.10
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  • Frost, R.L., Kristof, J. 1997. Intercalation of halloysite: A Raman spectroscopic study. Clays and Clay Minerals 45(4), 551-563. https://doi. org/10.1346/CCMN.1997.0450407
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An overview of halloysite mineral

Year 2023, Volume: 62 Issue: 4, 175 - 182, 12.02.2024

Emrah Durgut Mustafa Çınar Orhan Özdemir

https://doi.org/10.30797/madencilik.1364137

Abstract

Halloysite is a type of clay mineral found in the kaolin group together with kaolinite, dickite, and nacrite minerals. Kaolinite is the most common mineral in this group, while dickite, nacrite, and halloysite are rarer. Although halloysite is primarily used in ceramic production, application in other industries is increasing and gaining economic value due to its unique properties. The use of halloysite is determined by the degree of purity and the properties of the nano-sized tubular structure. Naturally obtained halloysite mineral has a key position in the field of nanotechnology due to its unique physicochemical properties originating from its tubular structure. Also, due to its reserves in many parts of the world, halloysite is a more economical material for the sectors compared to artificially produced nanomaterials. And, they find many different application areas because of these features (morphological and physicochemical). Halloysite reserves known in Türkiye are located in the Çanakkale and Balıkesir regions. Although there are many useful studies on halloysite in different, additional studies are needed to understand the nano-sized properties of halloysite ore and to ensure its use that will provide maximum benefit. This study aimed to contribute to the studies on halloysite in terms of literature by compiling studies on the characterization of halloysite minerals, reserve information, physicochemical properties, enrichment methods, and usage areas.

Keywords

Clay Halloysite Nanotechnology Characterization Enrichment

References

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  • Ambikadevi, V.R., Lalithambika, M. 2000. Effect of organic acids on ferric iron removal from iron-stained kaolinite. Applied Clay Science 16, 133-145. https://doi.org/10.1016/S0169-1317(99)00038-1 Andromeda Metals. 2019. An emerging force in industrial minerals.
  • https://announcements.asx.com.au/asxpdf/20191009/pdf/449bcwl4mzfpck. pdf [Accessed October 12, 2023].
  • Baba A.A, Mosobalaje M.A., Ibrahim A.S., Girigisu S., Eletta O.A.A, Aluko F.I., Adekola F.A. 2015. Bleaching of a Nigerian kaolin by oxalic acid leaching. Journal of Chemical Technology and Metallurgy 50(5), 623-630.
  • Başara, B., Saklar, S. 2015. Halloysite intercalation of northwest Anatolia. Bulletin of the Mineral Research and Exploration 150, 121-130.
  • https://doi.org/10.19111/bmre.44287
  • Belkassa K., Bessaha F., Marouf K., Batonneau I., Comparot J., Khelifa A. 2013. Physicochemical and adsorptive properties of a heat-treated and acid-leached Algerian halloysite. Colloids and Surfaces A: Physicochemical and Engineering Aspects 421, 26-33. https://doi. org/10.1016/j.colsurfa.2012.12.048 Berthier, P. 1826. Analyse de l’halloysite. Annales de Chimie et de Physique 32, 332-335.
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  • Bordeepong, S., Bhongsuwan, D., Pungrassami, T., Bhongsuwan, T. 2011. Characterization of halloysite from Thung Yai District, Nakhon Si Thammarat Province, in Southern Thailand. Songklanakarin Journal of Science and Technology 33(5), 599-607.
  • Bordeepong, S., Bhongsuwan, D., Pungrassami, T., Bhongsuwan, T. 2012. Mineralogy, chemical composition and ceramic properties of clay deposits in southern Thailand. Kasetsart Journal - Natural Science 46(3), 485-500.
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  • Carr, R.M., Chaikum, N., Patterson, N. 1978. Intercalation of Salts in Halloysite. Clays and Clay Minerals 26(2), 144-152. https://doi. org/10.1346/CCMN.1978.0260210
  • Churchman, G.J., Carr, R.M. 1975. The definition and nomenclature of halloysites. Clays and Clay Minerals 23(5), 382-388. https://doi. org/10.1346/CCMN.1975.0230510
  • Churchman, G.J., Theng, B.K.G. 1984. Interactions of halloysites with amides: mineralogical factors affecting complex formation. Clay Minerals 19(2), 161-175. https://doi.org/10.1180/claymin.1984.019.2.04
  • Churchman G.J., Whitton J.S., Claridge G.G.C., Theng B.K.G. 1984. Intercalation method using formamide for differentiating halloysite from kaolinite. Clays and Clay Minerals 32(4), 241-248. https://doi. org/10.1346/CCMN.1984.0320401
  • Churchman, G.J., Pasbakhsh, P., Lowe, D.J., Theng, B.K.G. 2016. Unique but diverse: some observations on the formation, structure and morphology of halloysite. Clay Minerals 51, 395-416. https://doi.org/10.1180/ claymin.2016.051.3.14
  • Chorover, J., Sposito, G., 1995. Surface charge characteristics of kaolinitic tropical soils. Geochimica et Cosmochimica Acta 59, 875-884. https:// doi.org/10.1016/0016-7037(94)00357-2
  • Clarke, G. 2008. Tubular clays. Industrial Minerals. March, 58-59.
  • Cravero, F., Maiza, P.J., Marfil, S.A. 2012. Halloysite in Argentinian deposits: origin and textural constraints. Clay Minerals 47(3), 329-340. https:// doi.org/10.1180/claymin.2012.047.3.04
  • Delvaux, B., Tessier, D., Herbillon, A., Burtin, G., Jaunet, A.-M., Vielvoye, L. 1992. Morphology, texture, and microstructure of halloysitic soil clays as related to weathering and exchangeable cation. Clays and Clay Minerals 40(4), 446-456. https://doi.org/10.1346/CCMN.1992.0400409
  • Demir, T.U., Altaş A. 2017. Determination of Tabanköy halloysite’s characteristics. 17.National Clay Symposium, 4-7 October 2017 Muğla, Muğla Sıtkı Koçman University, e-ISBN: 978-605-4397-62-4.
  • Dixon, J.B., McKee, T.R. 1974. Internal and external morphology of tubular and spheroidal halloysite particles. Clays and Clay Minerals 22, 127- 137. https://doi.org/10.1346/CCMN.1974.0220118
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Özdemir, O. 2022a.
  • Evaluation of different dispersants on the dispersion/sedimentation behavior of halloysite, kaolinite, and quartz suspensions in the enrichment of halloysite ore by mechanical dispersion. Minerals 20(11), 1426. https://doi.org/10.3390/min12111426
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Boylu. F., Özdemir, O. 2022b. Effect of blunging/dispersion parameters on separation of halloysite nanotubes from gangue minerals. Minerals 12(6), 683. https:// doi.org/10.3390/min12060683
  • Ece, O.I., Schroeder, P.A. 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area, Balikesir, Turkey. Clays and Clay Minerals 55(1), 18-35. https://doi.org/10.1346/CCMN.2007.0550102
  • Ece, O.I., Schroeder, P.A., Smilley, M.J., Wampler, J.M. 2008. Acid-sulphate hydrothermal alteration of andesitic tuffs and genesis of halloysite and alunite deposits in the Biga Peninsula, Turkey. Clay Minerals 43(2), 281-315. https://doi.org/10.1180/claymin.2008.043.2.10
  • Franco, F., Ruiz Cruz, M.D. 2004. Factors influencing the intercalation degree (‘reactivity’) of kaolin minerals with potassium acetate, formamide, dimethylsulphoxide and hydrazine. Clay Minerals 39(2), 193- 205. https://doi.org/10.1180/0009855043920130
  • Frost, R.L., Kristof, J. 1997. Intercalation of halloysite: A Raman spectroscopic study. Clays and Clay Minerals 45(4), 551-563. https://doi. org/10.1346/CCMN.1997.0450407
  • Garcia de Oliveira, M. T., Furtado, S. M., Formoso, M.L.L., Eggleton, R.A., Dani, N. 2007. Coexistence of halloysite and kaolinite - a study on the genesis of kaolin clays of Campo Alegre Basin, Santa Catarina State, Brazil.
  • Anais da Academia Brasileira de Ciências 79(4),665-681. https://doi. org/10.1590/S0001-37652007000400008
  • General Directorate of Mining and Petroleum Affairs. 2019. http://www. mapeg.gov.tr/Duyurular/duyuru_dukuman/obsf/2018-IV-A%20 Grubu%20OBSF.pdf (Accessed February 17, 2021).
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There are 70 citations in total.

Details

Primary Language English
Subjects Chemical-Biological Recovery Techniques and Ore Dressing
Journal Section Collection
Authors

Emrah Durgut 0000-0002-4637-7087

Mustafa Çınar 0000-0001-9553-423X

Orhan Özdemir 0000-0002-4408-546X

Publication Date February 12, 2024
Submission Date September 21, 2023
Published in Issue Year 2023 Volume: 62 Issue: 4

Cite

APA Durgut, E., Çınar, M., & Özdemir, O. (2024). An overview of halloysite mineral. Scientific Mining Journal, 62(4), 175-182. https://doi.org/10.30797/madencilik.1364137
AMA Durgut E, Çınar M, Özdemir O. An overview of halloysite mineral. Mining. February 2024;62(4):175-182. doi:10.30797/madencilik.1364137
Chicago Durgut, Emrah, Mustafa Çınar, and Orhan Özdemir. “An Overview of Halloysite Mineral”. Scientific Mining Journal 62, no. 4 (February 2024): 175-82. https://doi.org/10.30797/madencilik.1364137.
EndNote Durgut E, Çınar M, Özdemir O (February 1, 2024) An overview of halloysite mineral. Scientific Mining Journal 62 4 175–182.
IEEE E. Durgut, M. Çınar, and O. Özdemir, “An overview of halloysite mineral”, Mining, vol. 62, no. 4, pp. 175–182, 2024, doi: 10.30797/madencilik.1364137.
ISNAD Durgut, Emrah et al. “An Overview of Halloysite Mineral”. Scientific Mining Journal 62/4 (February 2024), 175-182. https://doi.org/10.30797/madencilik.1364137.
JAMA Durgut E, Çınar M, Özdemir O. An overview of halloysite mineral. Mining. 2024;62:175–182.
MLA Durgut, Emrah et al. “An Overview of Halloysite Mineral”. Scientific Mining Journal, vol. 62, no. 4, 2024, pp. 175-82, doi:10.30797/madencilik.1364137.
Vancouver Durgut E, Çınar M, Özdemir O. An overview of halloysite mineral. Mining. 2024;62(4):175-82.
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